SORPTION OF URANIUM FROM NITRIC ACID SOLUTION USING TBP-IMPREGNATED ACTIVATED CARBONS

Abstract

ABSTRACT The concept of extracuon chromatography has been used to study the sorption of uranium from nitric acid solutions using tri-n-butyl phosphate ( TBP) impregnated activated carbons. Batch equilibrium data and kinetic and breakthrough column behaviour of uranium are reported. Wood based activated carbon has shown better capacity and breakthrough characteristics than shell based activated carbon. Sorption rate on impregnated carbons was relatively slow indicating that diffusion is the rate controlling step within the pore structure of the activated carbon. Uranium distribution on impregnated activated carbons is compared with equivalent bulk liquid extraction and a mechansim of uranium sorption is discussed.