Publication | Closed Access
Solvent Effects on an Enzymatic Ester Synthesis in Supercritical Carbon Dioxide
44
Citations
6
References
1993
Year
Chemical EngineeringOleic AcidEnzymatic Ester SynthesisSolvent EffectsAggregation PhenomenonEngineeringNatural SciencesBiocatalysisSupercritical Carbon DioxideSupercritical Fluid ChromatographyBiochemical EngineeringEster SynthesisOrganic ChemistrySupercritical FlowCatalysisChemistrySupercritical Co2
Abstract The ester synthesis from oleic acid and (±)-citronellol by lipase was carried out in supercritical carbon dioxide(SC-CO2). In the near-critical region, the rate of reaction was considerably enhanced and (S)-(−)-oleic acid 3,7-dimethyl-6-octenyl ester was stereoselectively formed. The results were discussed with taking account of solvent properties of SC-CO2 and aggregation phenomenon about reacting species at high pressures.
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