Neutrale 30‐Valenzelektronen‐Tripeldeckerkomplexe mit <i>cyclo</i>‐E₅‐Mitteldeck (E = P, As)

Abstract

Neutral 30 Valence‐Electron Tripledecker Complexes with cyclo ‐E 5 Middle Deck (E = P, As) [1] In a stacking reaction of [(η 5 ‐E 5 )M(η 5 ‐C 5 Me 5 )] (3: E = P, As; M = Fe, Ru) with [M′(CO) 3 (NCMe) 3 ] ( 4 : M′ = Cr, Mo, W) at room temperature the neutral 30 valence‐electron tripledecker complexes [(η 5 ‐C 5 Me 5 )M(μ‐η 5:5 ‐E 5 ) M′(CO) 3 ] ( 5 ) are formed. Complexes 5b (M = Fe, E = P, M′ = Mo) and 5c, d (M = Fe, E = As, M′ = Cr, Mo) have been characterized by X‐ray structure analyses.