Inorganic Chemistry · 2010 · 45 citations · 45 references
Natural SciencesChemistryMaterials ScienceComputational ChemistryDrug DiscoveryOrganometallic ChemistryCoordination ChemistryLigand-based DesignMacromolecular AssemblySelf-assemblySelf-assembly Of NanomaterialsSupramolecular MaterialsCoordination PolyhedraCoordination Self-assemblyCoordination-driven Self-assemblyElectrospray IonizationMild Reaction ConditionsSupramolecular Coordination ComplexesTetrahedral ComplexesTetrahedral Coordination
The design and synthesis of coordinative truncated tetrahedra is described. The coordination-driven self-assembly of a truncated tetrahedron was achieved using 90° organoplatinum acceptors and a hexapyridyl ligand with six-fold symmetry under mild conditions. This tetrahedron can act as a host toward 1,3,5-triphenylbenzene. The truncated tetrahedral structures and the host-guest complex were identified using multinuclear ((31)P and (1)H) NMR spectroscopy, electrospray ionization mass spectrometry, X-ray crystallography, and pulsed-field-gradient spin-echo NMR, along with computational simulations.
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