Cocrystal Controlled Solid-State Synthesis of a Thermally Stable Nicotinate Analogue That Sustains an Isostructural Series of Porous Metal−Organic Materials

Abstract

An expanded analogue of nicotinic acid, HTriNA, can be prepared in high yield using cocrystal controlled solid-state synthesis and sustains porous bcu nets when coordinated to Co(II), Ni(II), Cu(II), and Cd(II).