Publication | Open Access
Selective Complexation of Li<sup>+</sup> in Water at Neutral pH Using a Self-Assembled Ionophore
73
Citations
6
References
2003
Year
EngineeringChemistryIon ProcessNeutral PhInorganic CompoundRuthenium ComplexSelective ComplexationInterfacial ChemistryBiophysicsInorganic ChemistryBiochemistryLi+/na+ SelectivityPhysical ChemistryInorganic SynthesisElectrochemistryTrinuclear MetallamacrocycleNatural SciencesCoordination ComplexIonic ConductorMolecular ComplexSelf-assembled IonophoreIon Structure
A trinuclear metallamacrocycle was obtained by assembly of a tridentate ligand and a ruthenium complex in water at neutral pH. The complex acts as a potent ionophore for lithium ions with a Li+/Na+ selectivity of 10 000:1.
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