Publication | Closed Access
Intercepting low oxidation state main group hydrides with a nucleophilic N-heterocyclic olefin
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Citations
34
References
2011
Year
Inorganic ChemistryMain Group HydridesEngineeringHeterocyclicBiochemistryNucleophilic N-heterocyclic OlefinNatural SciencesAlkene MetathesisOrganic ChemistrySufficient Lewis BasicityOrganometallic CatalysisCatalysisMain Group ChemistryChemistryHeterocycle ChemistryBiomolecular EngineeringLow Oxidation States
The N-heterocyclic olefin, IPr=CH(2) (IPr = [(HCNDipp)(2)C], Dipp = 2,6-(i)Pr(2)C(6)H(3)) has been demonstrated to be of sufficient Lewis basicity to stabilize main group hydrides in unusually low oxidation states.
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