The hydrothermal syntheses and characterization of one- and two-dimensional structures constructed from metal–organic derivatives of polyoxometalates: [{Cu(bpy)2}{Cu(bpy)(H2O)}(Mo5O15){O3P(CH2)4PO3}]·H2O and [{Cu2(tpypyz)(H2O)2}(Mo5O15)(O3PCH2CH2PO3)]·5.5H2O [bpy = 2,2′-bipyridine, tpypyz = tetra(2-pyridyl)pyrazine]

Abstract

The hydrothermal reaction of CuSO(4).5H2O, Na2MoO(4).2H2O and 2,2'-bipyridine with the bridging diphosphonate ligand H2O3P(CH2)4PO3H2 yields the one-dimensional chain [(Cu(bpy)2)(Cu(bpy)(H2O)2)(Mo5O15)(O3P(CH2)4PO3)].H2O; the introduction of a second bridging component in the reaction of Cu(MeCO2)2.H2O, MoO3, H2O3PCH2CH2PO3H2 and tetra(2-pyridyl)pyrazine yields the network solid [(Cu2(tpypyz)(H2O)2)(Mo5O15)(O3PCH2CH2PO3)].5.5H2O.