Direct Synthesis of the Novel 2-D Mixed-ligands Lead(II) Complex, Crystal Structure of [Pb(4,4′-bpy)(NO3)(SCN)]<i>n</i> (4,4′-bpy = 4,4′-bipyridine): (A New Polymeric Compound with Three Bridged Ligand and Inactive Lone Pair)

Abstract

Abstract A lead(II) complex with three ligands, 4,4′-bipyridine (4,4′-bpy), nitrate, and thiocyanate, has been synthesized and characterized by CHN elemental analysis, IR-, 1H-, 13C- and 207Pb NMR spectroscopy. The single-crystal X-ray data of [Pb(4,4′-bpy)(NO3)(SCN)]n compound shows that the complex to be two dimensional polymeric and the Pb atom has an eight-coordinate geometry. The lone pair of electrons on lead(II) is inactive in this complex.