Highly stereoelective polymerization of <i>rac</i>‐(<scp>D</scp>,<scp>L</scp>)‐lactide with a chiral schiff's base/aluminium alkoxide initiator

Abstract

Abstract A chiral Schiff's base/aluminium alkoxide initiator bearing a ligand derived from R ‐(+)‐1,1′‐binaphthyl‐2,2′‐diamine was synthesized and used for the stereoelective polymerization of rac ‐( D , L )‐lactide. Rather high stereoelectivity is observed: a polymer with 88% enantiomeric enrichment in D units is obtained at 19% conversion. At high conversions a stereocomplex between D‐ and L‐enriched stereocopolymers is formed. The polymerization reaction shows living type features, and narrow molecular weight distributions (M̄ w /M̄ n = 1,05–1,30) are obtained up to very high conversions. This indicates that transesterification reactions do not occur significantly with this sterically hindered initiator.