Concepedia

Dimanganese decacarbonyl/2-cyanoprop-2-yl-1-dithionaphthalate: toward sunlight induced RAFT polymerization of MMA

Xuelang Miao, Jiajia Li, Zhengbiao Zhang, Zhenping Cheng, Wei Zhang, Jian Zhu, Xiulin Zhu

Polymer Chemistry · 2014 · 23 citations · 40 references

DOI

Concepts

Abstract

Methyl methacrylate was polymerized in the presence of dimanganese decacarbonyl [Mn<sub>2</sub>(CO)<sub>10</sub>]/2-cyanoprop-2-yl-1-dithionaphthalate (CPDN) <italic>via</italic> a photo-induced controlled radical polymerization under visible (green LED with <italic>λ</italic><sub>max</sub> of 565 nm) or sunlight irradiation at a moderate temperature.

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