Publication | Closed Access
Reaction of Dichloromethyltris(trimethylsilyl)silane with Organolithium Reagents: Synthesis of an Intramolecularly Donor-Stabilized Silene
37
Citations
0
References
2000
Year
Inorganic ChemistryChemical EngineeringEngineeringNovel One-step ProcessSiliceneOrganometallic CatalysisChemistryTitle CompoundIntramolecularly Donor-stabilized SileneOrganometallic PolymerDetailed Structural AnalysisOrganolithium Reagents
In a novel one-step process, the intramolecularly donor-stabilized silene 1 is obtained by the reaction of the title compound with 8-dimethylamino-1-naphthyllithium. A detailed structural analysis has been carried out for 1, which is thermally stable up to 140 °C.