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ASYMMETRIC HYDROGENATION OF α-ACYLAMINOCINNAMIC ACID CATALYZED BY CHIRAL RHODIUM COMPLEXES. REMARKABLE EFFECTS OF HYDROGEN PRESSURE ON STEREOSELECTIVITY
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Citations
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References
1979
Year
Chemical EngineeringEngineeringHydrogen PressureChiral Rhodium ComplexesOrganic ChemistryPressure DependencyOrganometallic CatalysisCatalysisStereoselective SynthesisChemistryHomogeneous CatalysisAsymmetric CatalysisEnantioselective SynthesisAsymmetric Hydrogenation
Abstract Remarkable effects of hydrogen pressure on the stereoselectivity were observed in the asymmetric hydrogenation of α-acylaminocinnamic acid and its derivatives catalyzed by chiral rhodium complexes. Effects of added triethylamine on the pressure dependency of stereoselectivity was also studied. Possible mechanisms are proposed.
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