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Cyclic voltammetry studies on the complexation of metal cations by cryptands containing the ferrocene unit
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1989
Year
Materials ScienceInorganic ChemistryRare Earth MineralLn K2EngineeringMolecular ElectrochemistryFundamental ElectrochemistryMetal CationsOrganic ChemistryGeochemistryCyclic Voltammetry StudiesChemistryLanthanide Metal CationsFerrocene UnitElectrochemistryInorganic Compound
The co-ordination of alkaline-earth and lanthanide metal cations by a cryptand containing the ferrocene unit has been examined by cyclic voltammetry; the data are used to deduce values of K2 for the association of oxidised cryptand (1+) with this range of metal cations and a linear correlation between ln K2 and the ratio of ionic radius/ionic charge is reported.