Effect of ultrasound on extrusion of PP/EPDM blends: Structure and mechanical properties

Abstract

Abstract The effects of ultrasonic irradiation on the mechanical properties, morphology, and crystal structure of polypropylene (PP)/ethylene‐propylene‐diene terpolymer (EPDM) blends were examined. Results show that appropriate irradiation intensity can noticeably increase the toughness of the PP/EPDM blends without reducing rigidity. Scanning electron microscopic (SEM) observation shows that with ultrasonic irradiation, the morphology of a well‐dispersed EPDM phase is formed in the PP/EPDM blend. The glass transition temperatures of PP and EPDM phase approach each other as a result of ultrasonic irradiation. Differential Scanning Calorimetric (DSC) analysis indicates that the crystallinities of the PP and EPDM phases increase with ultrasonic irradiation, and β crystals of PP form in the PP/EPDM blend with ultrasonic irradiation, which is proven by wide angle X‐ray diffraction (WAXD) analysis. Polym. Eng. Sci. 44:1509–1513, 2004. © 2004 Society of Plastics Engineers.