Publication | Closed Access
C1−C5 Photochemical Cyclization of Enediynes
83
Citations
10
References
2002
Year
Chemical EngineeringBergman CyclizationNew Photochemical CyclizationFormal Hydrogen-atom AbstractionsPhotochemistryEngineeringMechanistic PhotochemistryHeterocyclicC1−c5 Photochemical CyclizationOrganic ChemistrySynthetic PhotochemistryChemistryHeterocycle Chemistry
This study reports a new photochemical cyclization of tetrafluoropyridinyl (TFP)-substituted enediynes that is accompanied with four formal hydrogen-atom abstractions from organic substrates and is mechanistically different from the Bergman cyclization.
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