Publication | Closed Access
[{1,3,5‐(CH<sub>3</sub>)<sub>3</sub>H<sub>3</sub>C<sub>6</sub>}<sub>6</sub>Tl<sub>4</sub>][GaBr<sub>4</sub>]<sub>4</sub> — Synthesis and Structure of a Mixed Mono‐ and Bis(arene)thallium Complex
58
Citations
12
References
1985
Year
Inorganic CompoundInorganic ChemistryCrystal StructureEngineeringMixed Mono‐Coordination ComplexStructure ElucidationMolecular ComplexThallium UnitsMain Group ChemistryChemistryCrystallographyTetrameric Tl 4Inorganic SynthesisBiomolecular EngineeringThallium ComplexSkeletal Framework
A tetrameric Tl 4 [GaBr 4 ] 4 skeletal framework, whose Tl ⊕ ions are alternately coordinated by one or two mesitylene molecules, is present in the title compound. It is formed from Tl[GaBr 4 ] and mesitylene and is the first complex containing both mono‐ and bis(arene)thallium units to be characterized by X‐ray analysis.
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