Prediction of thermodynamic properties of polar mixtures by a group solution model

Abstract

Abstract A modified group solution model for liquid mixtures is presented. The model differs from previous models in that the Bronsted‐Koefoed congruence principle is used to describe the effect of molecular size. The model has been tested for mixtures involving paraffin hydrocarbons, alcohols and water at low pressures. Such systems involve binary mixtures of the groups methylene and hydroxyl, and are reasonably represented by the model. Data presented enable the approximate equilibrium properties of such solutions at low pressures to be predicted at 40°C and 90°C. Interpolation and reasonable extrapolation from these temperatures should be satisfactory.