Thermodynamic Properties of Mixtures Containing Ionic Liquids. 2. Activity Coefficients at Infinite Dilution of Hydrocarbons and Polar Solutes in 1-Methyl-3-ethyl-imidazolium Bis(trifluoromethyl-sulfonyl) Amide and in 1,2-Dimethyl-3-ethyl-imidazolium Bis(trifluoromethyl-sulfonyl) Amide Using Gas−Liquid Chromatography

Abstract

Activity coefficients at infinite dilution of alkanes, alkenes, and alkylbenzenes as well as of the linear and branched C1−C6 alcohols, acetone, acetonitrile, ethyl acetate, alkyl ethers, and chloromethanes in the ionic liquids 1-methyl-3-ethyl-imidazolium bis(trifluoromethyl-sulfonyl) amide and 1,2-dimethyl-3-ethyl-imidazolium bis(trifluoromethyl-sulfonyl) amide were determined by gas chromatography using the ionic liquids as the stationary phase. The measurements were carried out at different temperatures between 313 K and 363 K. From the temperature dependence of the limiting activity coefficients partial molar excess enthalpies at infinite dilution of the solutes in the ionic liquids have been derived.