Publication | Closed Access
Ru‐Catalyzed Oxidation of Acetylenes to α‐Diketones with Iodosylbenzene
74
Citations
18
References
1981
Year
Carboxylic AcidsEngineeringCatalytic SynthesisOrganic ChemistryOrganometallic CatalysisCatalysisChemistryAbstract Disubstituted AcetylenesSynthetic ChemistryEnantioselective SynthesisBiomolecular Engineering
Abstract Disubstituted acetylenes are oxidized with PhIO in presence of Ru‐catalysts to afford α‐diketones in 65–85% yield. Under the same conditions terminal acetylenes are cleaved to carboxylic acids.
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