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Selective oxidation of sacrificial ethanol over TiO2-based photocatalysts during water splitting
128
Citations
34
References
2011
Year
Photohydrogen ProductionEngineeringBioenergyInorganic PhotochemistryEnergy ConversionGreen ChemistryPhoto-electrochemical CellChemistryPhotoelectrochemistryChemical EngineeringTio2 StructureSacrificial EthanolPhotocatalysisPhotosynthesisHealth SciencesSelective OxidationPhotochemistryCatalysisValuable Coupling ProductWater SplittingPhotoelectrocatalysisTio2-based Photocatalysts
The modulation of TiO2 structure can effectively alter the oxidation kinetics and pathway of sacrificial ethanol during the water-splitting reaction and dramatically adjust the selectivity of the valuable coupling product 2,3-butanediol from 0.0% to 96.6%, showing the possibility of photohydrogen production in green and economical indexes.
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