Concepedia

Facile New Synthesis of Chloroarsinidene Complexes

Joachim von Seyerl, U. MOERING, Adalbert Wagner, A De Bruijn Frank, Gottfried Hüttner

Angewandte Chemie International Edition in English · 1978 · 32 citations · 4 references

DOI

Concepts

Abstract

An extremely facile entry to functionalized chloroarsinidene complexes such as (1) is provided by the reaction shown below. The expected trigonal‐planar coordination of the arsenic was confirmed by X‐ray studies. equation image

References

4

C<sub>6</sub>H<sub>5</sub>P[Mn(CO)<sub>2</sub>C<sub>5</sub>H<sub>5</sub>]<sub>2</sub>: A Phosphinidene Complex with Trigonal Planar Coordinated Phosphorus(<scp>I</scp>)

Gottfried Hüttner, Hans‐Dieter Müller, Albin Frank et al. · Angewandte Chemie International Edition in English · 1975 · 67 citations

, , +12

Arsinidene Complexes: Structure and Electronic Spectrum of C<sub>6</sub>H<sub>5</sub>As[Cr(CO)<sub>5</sub>]<sub>2</sub>

Gottfried Hüttner, Joachim von Seyerl, Mario Marsili et al. · Angewandte Chemie International Edition in English · 1975 · 44 citations

, , +14

Arsinidene Complexes: Stabilization of Phenylarsanediyl, C<sub>6</sub>H<sub>5</sub>As, in C<sub>6</sub>H<sub>5</sub>As[Cr(CO)<sub>5</sub>]<sub>2</sub>

Gottfried Hüttner, Hans‐Georg Schmid · Angewandte Chemie International Edition in English · 1975 · 41 citations

, , +12

C<sub>6</sub>H<sub>5</sub>Sb[Mn(CO)<sub>2</sub>C<sub>5</sub>H<sub>5</sub>]<sub>2</sub>—The first Compound Containing Trigonal‐Planar Coordinated Antimony(<scp>I</scp>)

Joachim von Seyerl, Gottfried Hüttner · Angewandte Chemie International Edition in English · 1978 · 40 citations

, , +11