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Conversion of bonded cyclo-octadiene into a cyclo-octadienyl ligand and cleavage of boron–phenyl bonds of arene-bonded tetraphenylborate anions in ruthenium(<scp>II</scp>) systems: X-ray crystal and molecular structures of [Ru(η<sup>6</sup>-C<sub>6</sub>H<sub>5</sub>BL<sub>3</sub>)(1–3,5,6-η-C<sub>8</sub>H<sub>11</sub>)](L = Ph or F)
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1977
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Inorganic ChemistryChemical EngineeringX-ray CrystalEngineeringBiochemistryBonded Cyclo-octadieneNatural SciencesBoron–phenyl BondsCoordination ComplexOrganometallic CatalysisMolecular ComplexQuantum ChemistryChemistryMolecular ChemistryInorganic Synthesis
Labilisation of the hydrazine ligands in either [Ru(cod)(N2H4)4][BPh4]2(I; cod = cyclo-octa-1,5-diene) or [RuH(cod)(NH2NMe2)3][BPh4](II) in acetone produces [Ru(η6-C6H5BPh3)(1–3,5,6-η-C8H11)] which reacts with HA (A = BF4 or PF6) to give [Ru(η6-C6H5-BF3)(1–3,5,6-η-C8H11)]; a byproduct of the reaction with (II) is [Ru(cod)(C6H6)].