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Synthesis of the Central Tryptophan-Leucine Residue of Celogentin C
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2008
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Cross-coupling ReactionBiochemistryNatural SciencesPeptide SynthesisOrganic ChemistryCelogentin CPd-catalyzed Suzuki CouplingOrganometallic CatalysisCentral Tryptophan ResidueChemistryNatural Product SynthesisAsymmetric CatalysisSynthetic ChemistryEnantioselective Synthesis
The synthesis of the central tryptophan residue of celogentin C is described featuring a Pd-catalyzed imine/enamine Heck-type reaction, a Pd-catalyzed Suzuki coupling, and an asymmetric Rh-catalyzed hydrogenation.