Anodic trimerization: a facile one-step synthesis of tris(15-crown-5)triphenylene - Concepedia

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Anodic trimerization: a facile one-step synthesis of tris(15-crown-5)triphenylene

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References

1987

Year

Véronique Le Berre, L. Angély, N. SIMONET‐GUEGUEN, Jacques Simonet

Journal of the Chemical Society Chemical Communications

EngineeringAnodic TrimerizationOrganic ElectrochemistryHeterocyclicAromatic Ortho-diethersElectrochemistryElectrosynthesisOrganic ChemistryOrganometallic CatalysisChemistryNew Threefold IonophoreRemarkable Cyclic TrimerizationBiomolecular Engineering

Abstract

Under unusual non-nucleophilic conditions, aromatic ortho-diethers undergo a remarkable cyclic trimerization leading to hexasubstituted triphenylenes; in particular, the electrochemical synthesis of a new threefold ionophore is described.