Concepedia

Reversible Luminescence Switching of a Redox-Active Ferrocene–Europium Dyad

Manuel Tropiano, Nathan L. Kilah, Michael J. Morten, Habibur Rahman, Jason J. Davis, Paul D. Beer, Stephen Faulkner

Journal of the American Chemical Society · 2011 · 163 citations · 24 references

DOI

Concepts

Abstract

The copper-catalyzed cycloaddition reaction between a propargyl-appended europium complex and azidomethylferrocene yields a d-f dyad whose photophysical properties can be reversibly switched by varying the oxidation state of the ferrocene chromophore.

References

24

Non-radiative deactivation of the excited states of europium, terbium and ytterbium complexes by proximate energy-matched OH, NH and CH oscillators: an improved luminescence method for establishing solution hydration states

Andrew Beeby, Ian M. Clarkson, Rachel S. Dickins et al. · Journal of the Chemical Society Perkin Transactions 2 · 1999 · 1.4K citations

, , +16

Cell-Penetrating Metal Complex Optical Probes: Targeted and Responsive Systems Based on Lanthanide Luminescence

Craig P. Montgomery, Benjamin S. Murray, Elizabeth J. New et al. · Accounts of Chemical Research · 2009 · 701 citations · Full text

, , +23

Electronic structure of metallocenes

Harry B. Gray, Y. S. Sohn, Nicholas J. Hendrickson · Journal of the American Chemical Society · 1971 · 604 citations

, , +18

New Opportunities for Lanthanide Luminescence

Jean‐Claude G. Bünzli, Steve Comby, Anne‐Sophie Chauvin et al. · Journal of Rare Earths · 2007 · 535 citations · Full text

, , +5

Transition-metal sensitised near-infrared luminescence from lanthanides in d–f heteronuclear arrays

Michael D. Ward · Coordination Chemistry Reviews · 2006 · 415 citations

, , +7