Concepedia

Systematic Synthesis of Heterometallic Ni/Fe/S and Cu/Fe/S Clusters with a Pentlandite-like M<sub>8</sub>S<sub>6</sub> Core

Markos Koutmos, H. Kalyvas, Yiannis Sanakis, Athanasios Simopoulos, D. Coucouvanis

Journal of the American Chemical Society · 2005 · 12 citations · 19 references

DOI

Concepts

Abstract

The systematic synthesis of heterometallic Ni/Fe/S and Cu/Fe/S clusters with a M8S6 core structure that resembles that of pentlandite minerals is described. The chemical properties and electronic structures of the new clusters have been investigated and are reported in this communication.

References

19

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Jean Pierre Costes, Françoise Dahan, Jean Pierre Laurent · Inorganic Chemistry · 1985 · 138 citations

, , +11

Metal ion exchange reactions in cage molecules: the systems [M4-nM'n(SC6H5)10]2- (M, M' = Fe(II), Co(II), Zn(II), Cd(II)) with adamantane-like stereochemistry and the structure of [Fe4(SC6H5)10]2-

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Synthesis and stereochemistry of metal(II) thiolates of the types [M(SR)4]2-, [M2(SR)6]2-, and [M4(SR)10]2- (M = Fe(II), Co(II))

Karl S. Hagen, R. H. Holm · Inorganic Chemistry · 1984 · 78 citations

, , +9

Crystal chemistry of natural pentlandites

V. Rajamani, C. T. Prewitt · The Canadian Mineralogist · 1973 · 69 citations

, , +1

Refinement of the crystal structure of Co<sub>9</sub>S<sub>8</sub>

S. Geller · Acta Crystallographica · 1962 · 69 citations

, , +4