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Cyclophanes and [2]Catenanes as Ligands for Transition Metal Complexes: Synthesis, Structure, Absorption Spectra, and Excited State and Electrochemical Properties
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1998
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Inorganic ChemistryChemical EngineeringEngineeringTetracationic CyclophanesNatural SciencesCoordination ComplexDiversity-oriented SynthesisNovel Mono-Excited StateMolecular ComplexTransition Metal ComplexesElectrochemical PropertiesChemistryTransition MetalInorganic Synthesis
Two tetracationic cyclophanes and two [2]catenanes containing paraquat-type units together with one or two transition metal chelating 2,2′-bipyridyl moieties have been synthesized. The metal-binding units have been used to generate novel mono- and binuclear ruthenium(II), rhenium(I), silver(I) (right), and copper(I) complexes.