Journal of the American Chemical Society · 2006 · 24 citations · 3 references
Natural SciencesChemistryMaterials ScienceInorganic ChemistryPhysical ChemistrySolid-state ChemistryCoordination ChemistryCoordination NumberMetal OxidesMetal-ligand BondingTransition Metal ChemistryTransition Metal ComplexesComplex OxidesLayered Transition Metal OxidesMetal OxidationMetal Oxidation StatesOctahedral CoordinationOxidation State ChangesOxide StructureTransition Metal Oxides
The n = 3 Ruddlesden-Popper phase Sr3LaFe1.5Co1.5O10+/-delta is capable of sustaining O contents as low as O7.5 with a mean metal oxidation state of +2 and three coordination at the central site in the trilayer of originally octahedral transition metal sites. The shortening of the axial bonds to the flanking octahedral layers stabilizes the low oxidation state and consequent unusual low coordination number of the Fe2+ and Co2+ cations within the extended structure.
3
Catalytic Alkane Metathesis by Tandem Alkane Dehydrogenation-Olefin Metathesis
Alan S. Goldman, Amy H. Roy, Zheng Huang et al. · Science · 2006 · 589 citations