Concepedia

Rhodium-Catalyzed Carbonylation of 2-Alkynylbenzaldehyde under Water-Gas Shift Reaction Conditions: Formation of Novel Tricyclic Lactones

T. SUGIOKA, Shiwei Zhang, Noritsugu Morii, Takashi Joh, Shigetoshi Takahashi

Chemistry Letters · 1996 · 18 citations · 11 references

DOI

Concepts

Abstract

Abstract Rhodium complexes catalyze carbonylation of 2-alkynylbenzaldehyde 1 under water-gas shift reaction conditions to give novel lactone 2 as a major product (up to 59% yield), the structure of which is a tricyclic ring system.

References

11

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Reductions with carbon monoxide and water in place of hydrogen. 1. Hydroformylation reaction and water gas shift reaction

Hi Chun Kang, C. H. MAULDIN, T. Cole et al. · Journal of the American Chemical Society · 1977 · 191 citations

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Homogeneous catalysis of the water gas shift reaction by ruthenium and other metal carbonyls. Studies in alkaline solutions

Charles B. Ungermann, Vincent Landis, Sergio A. Moya et al. · Journal of the American Chemical Society · 1979 · 147 citations

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Homogeneous catalysis of the water-gas shift reaction

Richard M. Laine, Edward J. Crawford · Journal of Molecular Catalysis · 1988 · 108 citations

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Homogeneous catalysis of the water gas shift reaction using iron pentacarbonyl

A. D. King, R. B. King, D. Billy Yang · Journal of the American Chemical Society · 1980 · 95 citations

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