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Novel, electrolyte solutions comprising fully inorganic salts with high anodic stability for rechargeable magnesium batteries
443
Citations
10
References
2013
Year
ElectrolytesEngineeringElectrode-electrolyte InterfaceRechargeable Magnesium BatteriesElectrolyte SolutionsInorganic SaltsChemistrySalt ClassChemical EngineeringLewis Acidic CompoundsCorrosionSodium BatteryReversible Magnesium ElectrodepositionMaterials ScienceBattery AdditivesEnergy StorageSolid-state BatteryElectrochemical ProcessElectrochemistryMetal AnodeMagnesium-based CompositeBatteries
Herein the first inorganic magnesium salt solution capable of highly reversible magnesium electrodeposition is presented. Synthesized by acid-base reaction of MgCl2 and Lewis acidic compounds such as AlCl3, this salt class demonstrates upwards of 99% Coulombic efficiency, deposition overpotential of <200 mV, and anodic stability of 3.1 V.
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