Concepedia

A new method for generation of non-stabilized α-amino-substituted carbanions by the reaction of magnesium carbenoids with N-lithio arylamines: their reactivity and a new synthesis of α-amino acid derivatives

Tsuyoshi Satoh, Atsushi Osawa, Tohru Ohbayashi, Atsushi Kondo

Tetrahedron · 2006 · 13 citations · 47 references

DOI

Concepts

References

47

Spectroscopic Identification of Organic Compounds

Adel Μ. Awadallah · 2020 · 1.3K citations

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.alpha.-Lithioamine synthetic equivalents: syntheses of diastereoisomers from Boc derivatives of cyclic amines

Peter Beak, Won Koo Lee · The Journal of Organic Chemistry · 1993 · 262 citations

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(−)-Sparteine-Mediated α-Lithiation of <i>N</i>-Boc-<i>N</i>-(<i>p</i>-methoxyphenyl)benzylamine:  Enantioselective Syntheses of (<i>S</i>) and (<i>R</i>) Mono- and Disubstituted <i>N</i>-Boc-benzylamines

Yong Sun Park, Mark L. Boys, Peter Beak · Journal of the American Chemical Society · 1996 · 115 citations

, , +11

Anionic Cyclizations of α-Aminoorganolithiums. Determination of the Stereoselectivity at the Carbanion Center and the Synthesis of (+)-Pseudoheliotridane

Iain Coldham, Richard Hufton, David J. Snowden · Journal of the American Chemical Society · 1996 · 113 citations

, , +11

Magnesium alkylidene carbenoids: Generation from 1-halovinyl sulfoxides with Grignard reagents and studies on their property, mechanism, and some synthetic uses

Tsuyoshi Satoh, Koji Takano, Hiroyuki Ota et al. · Tetrahedron · 1998 · 107 citations

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