Rhodium-catalyzed hydroformylation of vinylidenic olefins: the different behaviors of the isomeric alkyl–metal intermediates as the origin of the β-regioselectivity

The asymmetric hydroformylation in the synthesis of pharmaceuticals

C. BOTTEGHI, Stefano Paganelli, A. Schionato et al. · Chirality · 1991 · 198 citations

Natural Sciences, Chemistry, Medicinal Chemistry +13

Catalysis by gold. Alkyl isomerization, cis-trans rearrangement, and reductive elimination of alkylgold(III) complexes

Akihiro Tamaki, S. A. Magennis, J.K. Kochi · Journal of the American Chemical Society · 1974 · 137 citations

Natural Sciences, Chemistry, Catalysis +11

(Chelating diphosphine)rhodium-Catalyzed Deuterioformylation of 1-Hexene: Control of Regiochemistry by the Kinetic Ratio of Alkylrhodium Species Formed by Hydride Addition to Complexed Alkene

Charles P. Casey, Lori M. Petrovich · Journal of the American Chemical Society · 1995 · 133 citations

Natural Sciences, Biochemistry, Chemistry +10

Regioselectivity in the rhodium-catalyzed hydroformylation of styrene as a function of reaction temperature and gas pressure

Raffaello Lazzaroni, Andrea Raffaelli, Roberta Settambolo et al. · Journal of Molecular Catalysis · 1989 · 105 citations

Natural Sciences, Chemical Engineering, Chemistry +15

Mechanistic Aspects of Asymmetric Hydroformylation of Olefins Catalyzed by Chiral Phosphine−Phosphite−Rhodium(I) Complexes

Toshihide Horiuchi, Eiji Shirakawa, Kyoko Nozaki et al. · Organometallics · 1997 · 97 citations

Natural Sciences, Chemistry, Catalysis +9