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THE STRUCTURE OF A NEW NATURAL APOTIRUCALLANE-TYPE TRITERPENE AND THE STEREOCHEMISTRY OF THE RELATED TERPENES. X-RAY AND 13C NMR SPECTRAL ANALYSES

Tsutomu Nakanishi, Akira Inada, Masatoshi Nishi, Takuichi Miki, Ryozi Hino, T. Fujiwara

Chemistry Letters · 1986 · 17 citations · 1 references

DOI

Concepts

Abstract

Abstract The structure of a new apotirucallane-type triterpene, 21-O-acetyl toosendantriol, isolated from the fruit of Melia toosendan was determined by X-ray analysis. Based on comparison of the 13C chemical shifts, the steric structures of the side chains of two epimeric 21-acetates derived from a tirucallane-type terpene, melianone were also clarified.

References

1

21,20‐Anhydromelianone and Melianone from Simarouba amara (Simaroubaceae); Carbon‐13 NMR Spectral Analysis of Δ<sup>7</sup>‐Tirucallol‐Type Triterpenes

Judith Polonsky, Zoïa Varon, Rosa M. Rabanal et al. · Israel Journal of Chemistry · 1977 · 34 citations

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