Concepedia

Preparation and properties of stable salts containing mono- or bis-(pentafluorophenyl)aurate(<scp>I</scp>) and mono-, tris-, or tetrakis-(pentafluorophenyl)aurate(<scp>III</scp>) ions

Rafael Usón, Antonio Laguna, José Vicente

Journal of the Chemical Society Chemical Communications · 1976 · 80 citations · 0 references

Concepts

Natural SciencesChemistryInorganic ChemistryOrganometallic ChemistryPhysical ChemistryChemical BondingChemical ReactionsCoordination ChemistryInorganic SynthesisMetal-ligand BondingTransition Metal ComplexesBonding In Coordination CompoundsComplexation ChemistryInorganic SaltsOrganometallic Complexes

Abstract

Tetrahydrothiophen (tht) and/or chloride may readily be displaced from [ClAu(tht)] or [Cl3Au(tht)] with LiC6F5 to give novel organometallic anionic complexes of gold(I) or gold(III).