Publication | Closed Access
Catalytic effect of a BH3: N,N-diethylaniline complex in the formation of alkenyl catecholboranes from alk-1-ynes and catecholborane
38
Citations
8
References
1990
Year
Asymmetric CatalysisEngineeringAlkene MetathesisCatalytic EffectAlkenyl CatecholboranesOrganic ChemistryN-diethylaniline ComplexOrganometallic CatalysisCatalysisChemistryHydroboration–alkenyl Transfer MechanismBiomolecular Engineering
Alkenyl catecholboranes are readily formed by the reaction of catecholborane and alk-1-ynes at 25°C, in the presence of 10 mol% of a BH3:N,N-diethylaniline complex, via a hydroboration–alkenyl transfer mechanism.
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