Concepedia

Insertion of Carbon Dioxide into (PCP)Pd<sup>II</sup>−Me Bonds

Roger Johansson, Martin Jarenmark, Ola F. Wendt

Organometallics · 2005 · 83 citations · 31 references

DOI

Concepts

Abstract

A (PCP)PdMe complex has been synthesized and structurally characterized, displaying a very long Pd−Me bond. It is reactive toward CO 2 insertion, giving the corresponding acetate in quantitative yield. The methyl complex can be regenerated using ZnMe 2, and catalytic carboxylation is possible in benzene.

References

31

Oxidative C−H Activation/C−C Bond Forming Reactions:  Synthetic Scope and Mechanistic Insights

Dipannita Kalyani, Nicholas R. Deprez, Lopa V. Desai et al. · Journal of the American Chemical Society · 2005 · 792 citations

, , +16

Selective Pd-Catalyzed Oxidative Coupling of Anilides with Olefins through C−H Bond Activation at Room Temperature

M.D.K. Boele, Gino P. F. van Strijdonck, André H. M. de Vries et al. · Journal of the American Chemical Society · 2002 · 615 citations · Full text

, , +16

The coordination chemistry of carbon dioxide and its relevance for catalysis: a critical survey

Walter Leitner · Coordination Chemistry Reviews · 1996 · 536 citations

, , +15

Recent developments in the activation of carbon dioxide by metal complexes

Xiaolong Yin, John R. Moss · Coordination Chemistry Reviews · 1999 · 517 citations

, , +12

Highly Active Pd(II) PCP-Type Catalysts for the Heck Reaction

Manuela Ohff, Andreas Ohff, Milko E. van der Boom et al. · Journal of the American Chemical Society · 1997 · 474 citations

, , +13