Concepedia

Spin Crossover Complex Film, [FeII(H-trz)3]-Nafion, with a Spin Transition around Room Temperature

Akio Nakamoto, Yuuki Ono, Norimichi Kojima, Daiju Matsumura, Toshihiko Yokoyama

Chemistry Letters · 2003 · 38 citations · 5 references

DOI

Concepts

Abstract

Abstract We have synthesized [FeII(H-trz)3]n complex film by using ion-exchange resin(Nafion) as counter anion, and have found the spin crossover phenomenon about at 260 K. Moreover, we have proved the existence of straight one-dimensional Fe chain structure of [FeII(H-trz)3]n on Nafion by means of EXAFS.

References

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