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Spin Crossover Complex Film, [FeII(H-trz)3]-Nafion, with a Spin Transition around Room Temperature
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Citations
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References
2003
Year
EngineeringMagnetic ResonanceChemistrySpintronic MaterialSpin DynamicSpin PhenomenonMagnetismSpin TransitionMaterials SciencePhysicsCounter AnionMagnetic MaterialSpin Crossover PhenomenonQuantum MagnetismSpintronicsFerromagnetismRoom TemperatureNatural SciencesCondensed Matter PhysicsApplied PhysicsIon-exchange Resin
Abstract We have synthesized [FeII(H-trz)3]n complex film by using ion-exchange resin(Nafion) as counter anion, and have found the spin crossover phenomenon about at 260 K. Moreover, we have proved the existence of straight one-dimensional Fe chain structure of [FeII(H-trz)3]n on Nafion by means of EXAFS.
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