Ruthenium Nanoparticles Stabilized by N‐Heterocyclic Carbenes: Ligand Location and Influence on Reactivity

Patricia Lara, Orestes Rivada‐Wheelaghan, Salvador Conejero, Romuald Poteau, Karine Philippot, Bruno Chaudret

Angewandte Chemie International Edition · 2011 · 225 citations · 32 references

Concepts

Abstract

NHCs go nano: Ruthenium nanoparticles were formed from (cyclooctadiene)(cyclooctatriene)ruthenium(0) and stabilized by N-heterocyclic carbenes (NHCs). Solid-state NMR spectroscopy revealed both the coordination of the NHC ligands on the surface of the particles and their surface reactivity.

References

32