Chemical Communications · 2009 · 138 citations · 44 references
Natural SciencesChemistryAnalytical ChemistrySensorsChemical SensorsFluorescence SpectroscopyMetal-ligand BondingOptical SpectroscopyTransition Metal ComplexesColorimetric ReadoutColorimetric SensorsFluorescence ProbesFluorescent Chemical ProbesFluorescent Probe DesignFluorescent ProbesFluorescent SensingSensitivity
A selective Pd probe is described, which shows fluorometric and colorimetric responses towards both Pd(2+) ions and Pd(0)-complexes with excellent sensitivity and potential application. The fluorescence quenching effect of Pd(2+) is inhibited by filling up d-orbitals after the reduction from Pd(2+) (open-shell) to Pd(0) (closed-shell).
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