Concepedia

Reductive elimination of C6F5–C6F5 in the reaction of bis(pentafluorophenyl)palladium(ii) complexes with protic acids

Take‐aki Koizumi, Atsuko Yamazaki, Takakazu Yamamoto

Dalton Transactions · 2008 · 35 citations · 55 references

DOI

Concepts

Abstract

Reductive elimination of C6F5-C6F5 from cis-[Pd(C6F5)2L] (L = cod, bpy, and dppb) was promoted by Brønsted acids. HNO3 is a convenient acid for the formation of C6F5-C6F5 from [Pd(C6F5)2(cod)]. The products are controlled by the auxiliary ligand.

References

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