Publication | Closed Access
Intramolecular Dehydrative Coupling of Tertiary Amines and Ketones Promoted by KO-<i>t</i>-Bu/DMF: A New Synthesis of Indole Derivatives
93
Citations
20
References
2013
Year
Cross-coupling ReactionKetones PromotedDerivativesEngineeringBiochemistryIndole DerivativesNatural SciencesOrganic ChemistryNew SynthesisTertiary AminesChemistryIntramolecular Dehydrative CouplingNatural Product SynthesisDerivative (Chemistry)Synthetic ChemistryBiomolecular Engineering
A new synthesis of indole derivatives has been achieved through intramolecular dehydrative coupling of tertiary amines and ketones promoted by KO-t-Bu/DMF. The reaction probably proceeds via an α-amino alkyl radical pathway.
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