Proceedings of the Physical Society Section A · 1952 · 1.7K citations · 0 references
Natural SciencesChemistryCrystal StructureElectromagnetismInorganic ChemistryAb Initio MethodsCrystal Field TheoryMagnetic Properties Of SolidsAngular Momentum AlgebraAngular Momentum OperatorsCrystal Field AnalysisCrystal-field EffectsMagnetic PropertiesRare-earth MagnetismWigner - Eckart TheoremWigner Function
An account is given of the methods used to determine the matrix elements of crystal field potentials with particular reference to rare earth ions. Emphasis is laid on the importance of Wigner coefficients in such problems and the idea of using equivalent angular momentum operators is developed. For convenience in applying the results tables of matrix elements are included.