Chemistry of Materials · 2001 · 628 citations · 70 references
Natural SciencesMaterials EngineeringMaterials ScienceMaterials ChemistryNanomaterialsOptical MaterialsFabrication MaterialsGlass MaterialsInorganic NanoparticlesNanocompositesOptical GlassesOptical Thin FilmsHigh-surface-area MaterialsMesoporous MaterialsMulti-step SynthesisOptical Sensor MaterialsProtective PackagingSensor ApplicationsSol-gel GlassesSurface Area
Mesostructured and mesoporous materials are emerging as a new class of optical materials. For mesostructured materials (inorganic/surfactant composites), prepared using a one-step synthesis procedure where the inorganic/surfactant/optically active species coassemble, the unique architecture provided by the surfactant−inorganic phase separation allows for higher concentrations compared to traditional sol−gel glasses and protective packaging of uniform three-dimensional arrays of optical species. The corresponding regularly arranged pores found in mesoporous materials (inorganic only) provide a high surface area to better disperse optically active components and allow for rapid diffusion for optical sensor applications. In this review, we discuss recent research results on the techniques used to produce optically functionalized mesostructured and mesoporous materials and the characterization of the final composites.
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Ordered mesoporous molecular sieves synthesized by a liquid-crystal template mechanism
Charles T. Kresge, M. E. Leonowicz, Wiesław J. Roth et al. · Nature · 1992 · 16.1K citations
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Natural Sciences, Materials Engineering, Materials Science +17