Rhodium-Catalyzed Addition/Ring-Opening Reaction of Arylboronic Acids with Cyclobutanones

Takanori Matsuda, Masaomi Makino, Masahiro Murakami

Organic Letters · 2004 · 104 citations · 10 references

Concepts

Abstract

Cyclobutanones react with arylboronic acids in the presence of a catalytic amount of Rh(I) complex to afford butyrophenone derivatives through the addition of an arylrhodium(I) species to the carbonyl group, followed by ring-opening of the resulting rhodium(I) cyclobutanolate. [reaction: see text]

References

10