Spin Canting and Metamagnetism in a 3D Homometallic Molecular Material Constructed by Interpenetration of Two Kinds of Cobalt(<scp>II</scp>)‐Coordination‐Polymer Sheets

Abstract

Two different types of coordination sheets made up of CoII ions, 3-hydroxypicolinate, and 4,4′-bipyridine interpenetrate to form a unique molecular-based magnetic material (see picture). This material displays a low-field metamagnetic transition and spin-canted behavior.