Publication | Closed Access
Syntheses and Structures of Phenyl-C<sub>81</sub>-Butyric Acid Methyl Esters (PCBMs) from M<sub>3</sub>N@C<sub>80</sub>
52
Citations
21
References
2009
Year
EngineeringNew 6,6-Open Phenyl-cHeterocyclicReactive SitesDiazoalkane Addition ReactionsOrganic ChemistryOrganometallic CatalysisChemistryPharmacologySynthetic ChemistryBiomolecular EngineeringNatural Product Synthesis
Two new 6,6-open phenyl-C(81)-butyric acid methyl ester metallofulleroids, M(3)N@C(80)PCBM (M = Sc, Y), were synthesized by diazoalkane addition reactions and fully characterized. The results demonstrate that the reactive sites are the same for M(3)N@C(80) (M = Sc, Y) but dramatically different from that of C(60).
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