Physical Review Letters · 2001 · 1.1K citations · 7 references
Natural SciencesMaterials ScienceMechanical Behavior Of MaterialsOptical MaterialsOpticsElastomeric PolymersNonlinear Optical MaterialsNonlinear OpticsOptical Properties Of SolidsPhotochromic MaterialsPlastic DeformationMolecular Conformation AnalysisPhotomechanical EffectsReversible Conformational ChangesShapeThermal Effects
We propose that large, reversible shape changes in solids, of between 10%-400%, can be induced optically by photoisomerizing monodomain nematic elastomers. Empirical and molecular analysis of shape change and its relation to thermal effects is given along with a simple model of the dynamics of response. Our experiments demonstrate these effects for the first time and theory is compared qualitatively with our results.
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