Publication | Closed Access
The First Molecular Superconductor Based on π-Acceptor Molecules and Closed-Shell Cations, [(CH3)4N][Ni(dmit)2]2, Low-Temperature X-Ray Studies and Superconducting Transition
180
Citations
2
References
1987
Year
Superconducting MaterialEngineeringBismuth-based SuperconductorsTheoretical Inorganic ChemistryChemistryClosed-shell CationsFirst Molecular SuperconductorSuperconductivityQuantum MaterialsRotational FreedomSuperconducting DevicesLow-temperature SuperconductivityImportant RoleHigh-tc SuperconductivityPhysicsπ-Acceptor MoleculesCrystallographyTransition Metal ChalcogenidesMethyl GroupHigh-temperature SuperconductivityNatural SciencesCondensed Matter PhysicsQuantum Superconductivity
Abstract Low-temperature structural study of [(CH3)4N][Ni(dmit)2]2 suggested that the rotational freedom of methyl group seems to play an important role in the “metal-semimetal” transition. Superconducting transition was observed at 5 K (7 kbar).
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