Ordered Honeycomb‐Structured Films from Dendronized PMA‐<i>b</i>‐PEO Rod‐Coil Block Copolymers

Abstract

Abstract Summary: Fabrication of honeycomb‐patterned films from amphiphilic dendronized block copolymer (PEO 113 ‐ b ‐PDMA 82 ) by ‘on‐solid surface spreading’ and ‘on‐water spreading’ method is reported. Highly ordered honeycomb films with quasi‐horizontally paralleled double‐layered structure can be fabricated by the on‐solid surface spreading method. This work raises the possibility that such structures can be formed in amphiphilic dendronized block copolymers and extends the family of source materials. magnified image